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6. Conclusions
The mechanochemical reactivity of different classes of pure compounds and binary systems has been discussed. The kinetics of mechanically-induced transformations has been investigated as a function of the main milling parameters. It has been found that conversion degree and conversion rates are related to the mass, size and velocity of the ball at impact as well as to the collision frequency and the vial charge. Simple general laws have been found relating the transformed mass fraction to the total mechanical work done on the processed powders. The generalization of these results to other chemical systems could permit a better, quantitative understanding of the mechanochemical processes.
Acknowledgements
The authors gratefully acknowledge Prof. S. Enzo for useful discussion. C. Deidda is also acknowledged for his continuous support. Thanks are due to MURST Rome and the University of Sassari for financial support.
The mechanochemical reactivity of different classes of pure compounds and binary systems has been discussed. The kinetics of mechanically-induced transformations has been investigated as a function of the main milling parameters. It has been found that conversion degree and conversion rates are related to the mass, size and velocity of the ball at impact as well as to the collision frequency and the vial charge. Simple general laws have been found relating the transformed mass fraction to the total mechanical work done on the processed powders. The generalization of these results to other chemical systems could permit a better, quantitative understanding of the mechanochemical processes.
Acknowledgements
The authors gratefully acknowledge Prof. S. Enzo for useful discussion. C. Deidda is also acknowledged for his continuous support. Thanks are due to MURST Rome and the University of Sassari for financial support.
6. 结论
纯粹化合物和二进位的系统不同班级的 mechanochemical 反应度已经被讨论。 动力学机械地- 感应变形已经被调查如主要的磨一个功能叁数。 资讯科技已经被发现，那一个转变程度和转变率在冲击和到碰撞频率对球的块，大小和速度被讲和玻璃小瓶费用。 简单的一般法律已经被发现关联那转换对在加工的粉上被做的总计机械的工作大众的分数。 对其他的化学系统的这些结果的一般化可以允许 mechanochemical 程序的比较好又数量理解。
承认
作家感激地承认教授。 为有用的讨论 S. Enzo。 C. Deidda 也被为他的连续支持承认。 谢谢为财政的支持是由于 MURST 罗马和 Sassari 的大学。
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