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People are puzzled____they read the book.
A the first time B at the first time
C for the first time D at first

You'd better make a mark____you have any questions.
A at which B at where C the place where

要解释清楚啊

C for the first time作时间状语,如用the first time应放句首啊
A at which 或用where作地点状语啊

1。A
我觉得这一句可以变一下:
The first time people read the book they are puzzled.the 我记得老师说过名词性短语(the first time)开头的句子前面好象不加介词我记得我老师还讲过一道相似的例题
2。B
这是一个定语从句,选后B的句子为
You'd better make a mark at where you have any questions.
at虽然放在where前面,但它实际应放在questions的后面,这个句子只不过把at提前了,整句也可变为
You'd better make a mark where you have any questions at.
我对我的答案只有80%的把握,我争取在你问题到期前去查查我的英语笔记,如果有误,我再争取告诉你

第一题选A,动词过去时后面直接跟名词。
第二题选B,which是哪个的意思,where才是哪里。

1.A
the first time是作时间状语,前面不要加任何介词,所以排除B和C选项;D选项不符合题意.

2.A
对于B选项,at多余了,where==in which==at which
对于C选项,the place 与where重复了.

1-A the first time直接做状语
2-A at which=where 介词at后不能跟where

1A 2 where